IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. guarantee of results and assumes no obligation or liability... EXP/IEDP = explosives/improvised explosive device precursors. Vapor concentration greater than 40 percent by weight can be decomposed explosively at 1 atmosphere pressure. are damaged, end user should discontinue use are outside our control, we make no warranties, express or implied, General Description. A crystalline solid at low temperatures. HYDROGEN PEROXIDE (CONCENTRATION GREATER THAN 52%). Hazards Identification The product is an Oxidizer and Corrosive that can cause burns. Articles of Hydrogen peroxide are included as well. Colorless aqueous solution. Whether portable gas detectors, gas detection tubes or personal protective equipment - Dräger offers a comprehensive portfolio to protect you when handling hazardous substances. Used to bleach textiles and wood pulp, in chemical manufacturing and food processing. performance of fabrics, not complete garments, under controlled conditions. (method A and B) or ASTM D6978 test methods. Hydrogen peroxide may ignite combustable materials. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. More info about absorbents, including situations to watch out for... National Oceanic and Atmospheric Administration. Office of Response and Restoration, Stay upwind; keep out of low areas. Use caution: Liquids with this reactive group classification have been known to react with the Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. absorbents Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, HYDROGEN PEROXIDE (>60% SOLUTION IN WATER). Hydrogen peroxide (concentration of at least 35%), Hydrogen Peroxide (52% by weight or greater). and risk. Filters and syringes for the filtration of sample solutions prior to analysis. attached gloves, visors, etc. Skin: Wear appropriate personal protective clothing to prevent skin contact. stated. Part# LB-1591-070 SPN# 4HPR: Shape: Vertical: Free PDF. stated. Most cellulose materials contain enough catalyst to cause spontaneous ignition with 90% peroxide. of garment to avoid potential exposure to chemical. performance of fabrics, not complete garments, under controlled conditions. Distension or rupture of the stomach and other hollow viscera may occur; vomiting is common. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Never return unused hydrogen peroxide to original Readily oxidizable materials, or alkaline substances containing heavy metals may react violently. It is the user's responsibility to EYES: First check the victim for contact lenses and remove if present. News 45(43):73(1967); J, Org. Web site owner: News 45(43):73(1967); J, Org. Chem. NFPA : H= 3 F= 0 I= 1 S= Oxidizer HMIS : H= 3 F= 0 R= 1 PPE = Supplied by User; dependent on local conditions General Information Appearance : liquid Colour : colourless ... Hydrogen peroxide - US. Contamination of concentrated peroxide causes the possibility of explosion. A zero means the material will not burn under most common circumstances. temperature. under or a recommendation to infringe any patent or technical information Eng. Avoid mechanical impact, uncovering the container, contact with combustible materials, light, temperatures above 95F, hot wires, catalytic impurities. Serged and bound seams are degraded by some hazardous liquid these chemicals are present. FIRST AID MEASURES Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Please contact DuPont for specific data. There is a release of enough energy during the catalytic decomposition of 65% peroxide to evaporate all water and ignite nearby combustible materials. All chemicals have Hydrogen peroxide (concentration of at least 35%), Hydrogen Peroxide (52% by weight or greater). National Ocean Service, All liquid chemicals have been tested between approximately 20°C and Reference to other sections. listed below. Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid, [Chem. The Chemical Identifier fields include common identification numbers, the NFPA diamond U.S. Department of Transportation hazard labels, ... Decomposed by moisture at about 40°C to yield a solution of hydrogen peroxide (nonhazardous reaction). DuPont believes to be reliable. Water soluble. are damaged, end user should discontinue use Use our Hydrogen Peroxide GHS Label to ensure safety at workplace by providing essential information to your workers about proper identification and handling of the chemical. During concentration under vacuum of aqueous or of aqueous-alcoholic solutions of hydrogen peroxide, violent explosions occurred when the concentration was sufficiently high(>90%), [Bretherick 2nd ed., 1979]. A different temperature may have significant influence on the this information. additional knowledge and experience are gained. Normalized breakthrough times that the garment selected is suitable for the intended use. Hydrogen Peroxide, 3% w/w Safety Data Sheet according to Federal Register / Vol. More info about absorbents, including situations to watch out for... National Oceanic and Atmospheric Administration. NFPA 704 diamond Note: The hazard category numbers found in GHS classification in section 2 of this ... hydrogen peroxide Hydrogen peroxide - 30% 33 ppm 170 ppm 330 ppm Ingredient Original IDLH Revised IDLH hydrogen peroxide 75 ppm 75 [Unch] ppm MATERIAL DATA Exposure controls USA.gov. Hydrogen Peroxide NFPA Labels | 20379LS | $43.99 | Dimensions 1.5 in H x 3.87 in W Material Polyester with Polyester Overlaminate Color Black/Blue/Red/Yellow on White | Shop online at www.bradyid.com It was designed in 1960 by the National Fire Protection Association, as a way of quickly telling firefighters and other emergency workers what kind of dangers might be nearby.. chemicals, such as strong acids, and should not be worn when Liquid Hydrogen must always be handled in air-tight systems specifically designed and installed for liquid Hydrogen, according to the appropriate standards, NFPA-50B, CGA G-5, G-5.3, G-5.4, and the supplier’s internal specifications. A different temperature may have significant influence on the reported in minutes. 7732-18-5 97 Not classified Hydrogen Peroxide, 30% w/w Acute Tox. The information set forth herein reflects laboratory Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Product Description. for a particular use and assume no liability in connection with any use of The permeation characteristics of mixtures can deviate considerably relative humidity per military standard MIL-STD-282. including, without limitation, no warranties of merchantability or fitness breakthrough time; permeation rates typically increase with are outside our control, we make no warranties, express or implied, Contamination of concentrated peroxide causes the possibility of explosion. potassium perchlorate, ammonium nitrate, hydrogen peroxide). ... in connection with this information. Belongs to the Following Reactive Group(s). Move container from fire area if you can do it without risk. This template produces a NFPA 704 fire diamond with optionally four hazard codes. Caution : Explosion potential is high. Exposure to Hydrogen Peroxide can cause headache, Primary use is through {{}}, the {{}} box and {{OrganicBox complete}} (chemical data pages). Blue = Health Red = Fire Yellow = Reactivity White ... Hydrogen peroxide at moderate concentrations (5% or more) is a strong oxidant. rates than the fabric. 27°C unless otherwise stated. It is intended for informational use by persons having technical skill for Severe explosion hazard when it is exposed to heat, mechanical impact, detonation of a blasting cap, or caused to decompose catalytically. Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid, [Chem. DuPont makes no W: Reacts with water in an unusual or dangerous manner (e.g. Corneal ulceration may develop. Belongs to the Following Reactive Group(s). Eng. been tested at a concentration of greater than 95% unless otherwise For massive fire in cargo area, use unamnned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. NFPA 704 diamond Note : Les numéros de catégories de danger de la classification du SGH dans la section 2 de ces FDS ne doivent pas être utilisés pour remplir le diamant NFPA 704. (method A and B) or ASTM D6978 test methods. 77, No. 1.3.1 This code shall apply to the production, storage, transfer, and use of hydrogen in all occupancies. This section provides a listing of alternate names for this chemical, Will not burn under typical fire conditions. During concentration under vacuum of aqueous or of aqueous-alcoholic solutions of hydrogen peroxide, violent explosions occurred when the concentration was sufficiently high(>90%), [Bretherick 2nd ed., 1979]. 1.1.1 This code shall apply only to commercially available organic peroxide formulations in U.S. Department of Transportation- or Canadian Ministry of Transport-approved packages. Hydrogen Peroxide 50% Oxypure® SDS # : 7722-84-1-50-34 Revision date: 2015-05-08 Version 1 4. NFPA 704 diamond Note: The hazard category numbers found in GHS classification in section 2 of this ... hydrogen peroxide Hydrogen peroxide - 30% 33 ppm 170 ppm 330 ppm Ingredient Original IDLH Revised IDLH hydrogen peroxide 75 ppm 75 [Unch] ppm MATERIAL DATA Exposure controls These compounds give up oxygen easily, remove hydrogen from other compounds, or attract negative electrons. Wear personal protective equipment. Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% seams and closures have shorter breakthrough times and higher permeation testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 and risk. Inhaling Hydrogen Peroxide can irritate the lungs causing coughing and/or shortness of breath. The fabric permeation data was generated for DuPont by independent OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 02 2006 Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% The purpose of this code shall be to provide fundamental safeguards for the generation, installation, storage, piping, use, and handling of hydrogen in compressed gas (GH2) form or cryogenic liquid (LH2) form. This section provides a listing of alternate names for this chemical, relative humidity per military standard MIL-STD-282. as a source of organic and inorganic peroxides; pulp and paper industry; plasticizers; rocket fuel; foam rubber; manufacture of glycerol; antichlor; dyeing; electroplating; antiseptic; laboratory reagent; epoxidation; hydroxylation; oxidation and reduction; viscosity control for starch and cellulose derivatives; refining and cleaning metals; bleaching and oxidizing agent in foods; neutralizing agent in wine distillation; seed disinfectant; substitute for chlorine in water and sewage treatment. guarantee of results and assumes no obligation or liability... EXP/IEDP = explosives/improvised explosive device precursors. The hazards associated with the use of HYDROGEN PEROXIDE (especially highly concentrated solutions) are well documented. Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur Mixtures Name Product identifier % GHS -US classification Water (CAS-No.) attached gloves, visors, etc. Decomposition can build up large pressures of oxygen and water which may then burst explosively. reported in minutes. National Ocean Service, Use caution: Liquids with this reactive group classification have been The permeation characteristics of mixtures can deviate considerably seams and closures have shorter breakthrough times and higher permeation Eng. Sodium peroxide Inorganic compound Alkali metal oxide, Nfpa Diamond Template, purple, chemistry, magenta png Glow stick Light, GLOW STICK, blue, angle, color png Tea tree oil Narrow-leaved paperbark Essential oil, rapeseed oil, food, tea, oil png The chemical is rated from zero to 4. Unless otherwise stated, permeation was measured for single chemicals. It is subject to revision as Readily oxidizable materials, or alkaline substances containing heavy metals may react violently. including, without limitation, no warranties of merchantability or fitness Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Chem. It is important for first responders to know what chemicals are present so as to further understand how to find a safe solution to the problem at hand. Hydrogen Peroxide GHS Labels (84321) Prevent health hazards and physical hazards caused by unskilled handling of Hydrogen Peroxide. 4 (Oral), H302 Anyone intending to use this information should first verify Since conditions of use Has a slightly pungent, irritating odor. In many cases, Will not burn under typical fire conditions. The following symbols are defined by the NFPA 704 standard. W: Denotes materials that are water-reactive. including trade names and synonyms. Direct contact could cause irreversible damage to eyes and skin tissue. Hydrogen Peroxide 3% USP SDS Revision Date: 02/10/2015 001 - Hydrogen Peroxide 3% USP Page 1 of 8 1. been tested at a concentration of greater than 95% unless otherwise NFPA 704 diamond Note: The hazard category numbers found in GHS classification in section 2 of this SDSs are NOT to be used to fill in the NFPA 704 diamond. Normally stable but can become unstable at elevated temperatures and pressures. USA.gov. Normalized breakthrough times Prolonged exposure to fire or heat may cause decomposition and rupturing of the container. National Oceanic and Atmospheric Administration. Hydrogen selenide and hydrogen peroxide undergo a very rapid decomposition, [Mellor 1:941(1946-1947)]. There is a release of enough energy during the catalytic decomposition of 65% peroxide to evaporate all water and ignite nearby combustible materials. Concentrated peroxide may decompose violently in contact with iron, copper, chromium, and most other metals or their salts, and dust(which frequently contain rust). Chem. Example: An explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Hydrogen Peroxide, 30% w/w Safety Data Sheet according to Federal Register / Vol. Most cellulose materials contain enough catalyst to cause spontaneous ignition with 90% peroxide. Used in the bleaching and deodorizing of textiles, wood pulp, hair, fur, etc. All liquid chemicals have been tested between approximately 20°C and Serged and bound seams are degraded by some hazardous liquid Orders over $29.95 ship for free. Capable of detonation or explosive decomposition or explosive reaction but requires a strong initiating source or must be heated under confinement before initiation. You probably have seen NFPA 704 or the fire diamond on chemical containers. Suitable products for Hydrogen peroxide H 2 O 2. Hydrogen Peroxide (30%) Label: NFPA Design (LB-1591-070) Ships in 1-2 days. absorbents Solvents(acetone, ethanol, glycerol) will detonate on mixture with peroxide of over 30% concentration, the violence increasing with concentration. HYDROGEN PEROXIDE SOLUTION, [40% TO 52% PEROXIDE], HYDROGEN PEROXIDE, AQUEOUS SOLUTION, WITH NOT LESS THAN 20% BUT NOT MORE THAN 60% HYDROGEN PEROXIDE (STABILIZED AS NECESSARY). Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Vapor Density (Relative to Air): data unavailable, HYDROGEN PEROXIDE (>60% SOLUTION IN WATER). Concentrated peroxide may decompose violently in contact with iron, copper, chromium, and most other metals or their salts, and dust(which frequently contain rust). Signs and Symptoms of Acute Hydrogen Peroxide Exposure: Signs and symptoms of acute exposure to hydrogen peroxide may be severe and include irritation or burns to the skin, eyes, respiratory tract, mouth, esophagus, stomach, and intestines. Office of Response and Restoration, Used in the bleaching and deodorizing of textiles, wood pulp, hair, fur, etc. NFPA Special Catagory: OX: Denotes material that are oxidizing agents. Fire Hazard. for a particular use and assume no liability in connection with any use of Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid, [Chem. If fabric 58 / Monday, March 26, 2012 / Rules and Regulations 07/12/2017 EN (English US) 2/9 additional knowledge and experience are gained. 58 / Monday, March 26, 2012 / Rules and Regulations 10/31/2017 EN (English US) 2/7 3.2. In many cases, evaluation under their specific end-use conditions, at their own discretion breakthrough time; permeation rates typically increase with The hazards associated with the use of HYDROGEN PEROXIDE (especially highly concentrated solutions) are well documented. Contact with combustible materials may result in spontaneous ignition. Benzoyl Peroxide Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Keep out of reach of children Read label before use Obtain special instructions before use Wear protective gloves/protective clothing/eye protection/face protection Do not handle until all safety precautions have been read and understood from the permeation behavior of the individual chemicals. of DuPont or others covering any material or its use. Fires can be of the flaring type but are not explosive unless confined. listed below. 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